期刊名称：Pertanika Journal of Social Sciences & Humanities
印刷版ISSN：0128-7702
电子版ISSN：2231-8534
出版年度：1980
卷号：3
期号：2
出版社：Universiti Putra Malaysia
摘要：Various high-energy modification and crystalline hydrates of Tutton s salts containing Mn(II), Ni(II)and Zn(II) have been prepared and their heats of solution measured. The energy difference of the anhydrous salts given in kjjmole of hexahydrate have been assigned as 10Dqs for the complexes. The values obtained have been compared with the ligand field splitting energies of the complexes in the sulphate salts. The discrepancies were explained in terms of the presence of ammonium ions in the lattice which may have reduced the electron density on the coordinated water molecules.
关键词：Ligand field splitting energy - of hexaaquomanganese (II) - of hexaaquonickel(II) - of hexaaquozinc (II); Tutton's salt - ligand field splitting energies - heat of solution; Heat of solution - of Tutton's salt
