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  • 标题:Solvent Free One-Pot Synthesis of 1,2,4,5-Tetrasubstituted Imidazoles Catalyzed by Secondary Amine Based Ionic Liquid and Defective Keggin Heteropoly Acid
  • 本地全文:下载
  • 作者:Pranab Jyoti Das ; Jupitara Das ; Munni Ghosh
  • 期刊名称:Green and Sustainable Chemistry
  • 印刷版ISSN:2160-6951
  • 电子版ISSN:2160-696X
  • 出版年度:2013
  • 卷号:3
  • 期号:4A
  • 页码:6-13
  • DOI:10.4236/gsc.2013.34A002
  • 出版社:Scientific Research Publishing
  • 摘要:Secondary amine based ionic liquid and defective Keggin type heteropoly acid (HPA) are separately used for efficient one-pot four-component synthesis of 1,2,4,5-tetrasubstituted imidazoles assisted by microwave (MW). Eco-friendly solvent free procedure, short reaction time, high yield of products and reusability of catalysts are important features of the synthesis. A comparative study on the efficiency of the two catalysts is reported. This work further demonstrates the alternate use of urea, instead of often used ammonium acetate, as source of nitrogen.
  • 关键词:Ionic Liquids; Keggin Heteropolyacid; Microwave; Tetrasubstituted Imidazole; Solvent Free Synthesis; Multicomponent Reaction
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