期刊名称：Journal of Environmental and Occupational Science
印刷版ISSN：2146-8311
出版年度：2012
卷号：1
期号：1
页码：47-52
DOI：10.5455/jeos.20120501110036
语种：
出版社：International Medical Journal Management and Indexing System
摘要：Simultaneous desulfurization and denitrification has been investigated using FeCo/zeolite as catalyst. The reaction efficiency of microwave catalytic reduction of SO2 and NOx with ammonium bicarbonate (NH4HCO3) as a reducing agent could be up to 96 and 90.6%, respectively. A microwave reactor with FeCo/zeolite only could also be used to microwave catalytic radical oxidative 91% SO2 to sulfate and 84.3% NOx to nitrates. Microwave catalytic desulfurization and dentrification effect on FeCo/zeolite is slightly higher than that of catalytic reduction of SO2 and NOx using ammonium bicarbonate as reducing agent and FeCo/zeolite as catalyst. The mechanism for microwave-induced SO2 and NOx reduction can be described as the microwave induced catalytic reaction between SO2, NOx, and ammonium bicarbonate, with SO2, NOx, and ammonium bicarbonate, with FeCo/zeolite being the catalyst and microwave absorbent. Microwave catalytic removal of SO2 and NOx over FeCo/zeolite catalyst follows LangmuirâHinshelwood (L-H) kinetics.
