出版社：Defence Scientific Information & Documentation Centre
摘要：Polarographic behaviour of Cd/sup 2/+ with a schiff base salicyladehyde trisbuffer has been studied in DMF water media of three different compositions (viz., 0%, 30% and 50% v/v of DMF). Stability constant, free energy change delta G, enthalpy change delta H and entropy change delta S of the systems are calculated for all the three media at three different temperatures (viz., 30 degree centigrade, 40 degree centigrade and 50 degree centigrade). A relation of halfwave potential of the system with the dielectric constant of the medium has also been verified.
关键词：Polarographic behaviour;DMF water media;Dielectric constant
