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  • 标题:Stereospecific Synthesis of trans-t-Butyl Beta-Methyl-Beta-(p-Bromophenyl)-Glycidate and its Pyrolysis
  • 本地全文:下载
  • 作者:R. K. Bansal ; K. Sethi
  • 期刊名称:Defence Science Journal
  • 印刷版ISSN:0976-464X
  • 出版年度:2014
  • 卷号:29
  • 期号:4
  • 页码:151-152
  • DOI:10.14429/dsj.29.6507
  • 语种:English
  • 出版社:Defence Scientific Information & Documentation Centre
  • 摘要:trans-t-Butyl Beta-(p-bromophenyl)-glcidate has been synthesised by the stereospecific epoxidation of the unsaturated ester (V)using m-chloroperbenzoic acid. The trans-configuration was assigned on the basis of spectral analysis and comparison with the similar product obtained in the Darzens condensation. The ester on pyrolysis yields a-methyl a- (p-bromophenyl) acetaldehyde.
  • 关键词:Darzens condensation;Chloroperbenzoic acid
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